TextLabel transparency tween script doesn't work

It’s because you’re using StarterGui. You need to access the PlayerGui to edit GUIs, as StarterGui is just where the server stores GUIs.
And for proper function, this script should be a local script, and contain a debounce on the .Touched() event so that it doesn’t run like 100 times in one second (which is what would happen if there were no debounce).

Note: If you just put the local script in the gui, you don’t need to worry about “accessing the playerGUI” since you can just use script.Parent index method.